Download E-books Chemical Thermodynamics: Basic Concepts and Methods PDF

By Irving M. Klotz

  • A thoroughly up to date, extended version of a longstanding and influential textual content on chemical thermodynamics
  • Covers the logical foundations and interrelationships of thermodynamics and their software to difficulties which are quite often encountered via the chemist.
  • Explanations of summary options in a transparent and straightforward, but nonetheless rigorous fashion
  • Logical association of the cloth to facilitate studying, together with labored out examples.
  • Computational strategies, graphical, numerical, and analytical, are defined totally and are used usually, either in illustrative and in assigned problems.

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0572 zero. 0364 20. 02595 a thousand – 5000 2. 7339 1. 47478 20. 04767 zero. 00782 20. 000479 HD(g) 50 – one thousand three. 893 23. 508 1. 083 21. 337 zero. 580 a thousand – 5000 zero. 595 five. 538 20. 324 zero. 084 20. 008 O2(g) 50 – one thousand three. 6297 21. 7943 zero. 6579 20. 6007 zero. 17861 a thousand – 5000 three. 4480 1. 08016 20. 04187 zero. 00919 20. 000763 N2(g) 50 – a thousand three. 5385 20. 2611 zero. 0074 zero. 1574 20. 09887 one thousand – 5000 2. 8405 1. 64542 20. 06651 zero. 01248 20. 000878 Cl2(g) 50 – a thousand three. 0560 five. 3708 20. 8098 zero. 5693 20. 15256 a thousand – 5000 four. 1967 zero. 54228 20. 03370 zero. 01108 20. 001205 Br2(g) 50 – one thousand three. 2118 7. 1600 21. 5277 1. 4446 20. 49867 a thousand – 5000 four. 8113 20. 57566 zero. 03856 20. 00696 zero. 000303 H2O(g) 50 – one thousand four. 395 24. 186 1. 405 21. 564 zero. 632 a thousand – 5000 zero. 507 7. 331 20. 372 zero. 089 20. 008 CO2(g) 50 – one thousand three. 259 1. 356 1. 502 22. 374 1. 056 a thousand – 5000 zero. 269 eleven. 337 20. 667 zero. 167 20. 015 CO(g) 50 – a thousand three. 912 23. 913 1. 182 21. 302 zero. 515 one thousand – 5000 zero. 574 6. 257 20. 374 zero. 095 20. 008 CNCl(g) 298 – a thousand 2. 541 15. 740 22. 713 2. 354 20. 787 HCl(g) 50 – one thousand three. 827 22. 936 zero. 879 21. 031 zero. 439 one thousand – 5000 zero. 578 five. 777 20. 336 zero. 085 20. 008 DCl(g) 50 – one thousand three. 917 23. 965 1. 205 21. 323 zero. 521 a thousand – 5000 zero. 567 6. 328 20. 378 zero. 096 20. 009 sixty five (Continued) sixty six desk four. nine persisted Temperature a / / / / 1 a2 a3 a4 Substance Range/K a 1023 ok 1025 K2 1028 K3 1021 K4 zero SO2(g) 50 – a thousand four. 147 22. 234 2. 344 23. 271 1. 393 one thousand – 5000 zero. 391 eleven. 636 20. 713 zero. 183 20. 016 SO3(g) 50 – a thousand three. 426 6. 479 1. 691 23. 356 1. 590 a thousand – 5000 zero. 233 sixteen. 771 21. 023 zero. 261 20. 023 CH4(g) 50 – a thousand four. 568 28. 975 three. 631 23. 407 1. 091 a thousand – 5000 zero. 282 12. 718 20. 520 zero. one hundred and one 20. 007 C2H6(g) 50 – one thousand four. 178 24. 427 five. 660 26. 651 2. 487 one thousand – 5000 zero. 001 eleven. 202 1. 928 22. 205 zero. 628 C3H8(g) 50 – one thousand three. 847 five. 131 6. 011 27. 893 three. 079 one thousand – 5000 zero. 001 19. 052 2. 087 22. 682 zero. 785 n-C4H10(g) 2 hundred – one thousand five. 547 five. 536 eight. 057 210. 571 four. 134 one thousand – 1500 zero. 006 24. 568 2. 855 23. 659 1. 076 n-C5H12(g) 2 hundred – one thousand 7. 554 20. 368 eleven. 846 214. 939 five. 753 one thousand – 1500 zero. 008 24. 320 five. one hundred seventy 25. 975 1. 751 Benzene(g) 50 – one thousand three. 551 26. 184 14. 365 219. 807 eight. 234 a thousand – 1500 zero. 001 222. 947 14. 018 212. 663 three. 469 Pyridine(g) 298 – one thousand 23. 505 forty nine. 389 21. 746 21. 595 1. 097 Carbon (graphite) 50 – four hundred 21. 30031 21. 18994 210. 16834 26. 66831 225. 41989 four hundred – 5000 zero. 037945 four. 450695 20. 241501 zero. 056079 20. 004567 aReprinted with permission from Ref. four, pp. 532–537, pp. 575–717. See additionally ok. ok. Kelley, U. S. Bur. Mines Bulletin 476 (1949) and 584 (1960); NIST Chemistry WebBook: at http://webbook. nist. gov/chemistry/. four. five warmth capability sixty seven warmth Capacities of Solids Early within the 19th century, Dulong and Petit saw that the molar warmth ability of an outstanding aspect typically is close to 6 cal mol21 K21 (25 J mol21 K21). next research confirmed that CVm (or CPm) varies markedly with the temperature, within the type indicated through determine four.

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