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A few two decades in the past, i used to be privileged to proportion in writing a ebook at the descriptive chemistry of the 4d, 5d, 4f and 5f metals that integrated those 8 parts inside of its compass (S.A. Cotton and F.A. Hart, The Heavy Transition components, Macmillan, 1975). This quantity stocks an identical objective of protecting the descriptive chemistry of silver, gold and the six platinum metals in a few aspect at a degree compatible for complex undergraduate and postgraduate learn. It doesn't try to be a finished treatise at the chemistry of those metals. It makes an attempt to fill a slot among the final textual content and the in-depth evaluation or monograph. The organometallic chemistry is restrained to a-bonded com­ kilos in common oxidation states; compounds with IT-bonding ligands are usually excluded. Their inclusion might have elevated the size of the e-book significantly and, in addition, their contemporary chemistry has been broadly and expertly reviewed within the new entire Organometallic Chemistry, II, eds G. Wilkinson, F.G.A. Stone and E.W. Abel, Pergamon, Oxford, 1995.

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Silver and Gold .............................................................. 273 four. 1 creation ..................................................................... 273 four. 2 the weather and makes use of .................................................. 274 four. 2. 1 Extraction ...................................................... 275 This web page has been reformatted through Knovel to supply more straightforward navigation. x Contents four. 2. 2 four. three Gold Plating and different tools of Gold Deposition ..................................................... 276 Halides ............................................................................ 276 four. three. 1 Silver Halides ................................................ 276 four. three. 2 Gold Halides .................................................. 279 four. four Oxides and different Binary Compounds ............................ 282 four. five Aqua Ions ........................................................................ 283 four. 6 Silver(I) Complexes ......................................................... 285 four. 6. 1 Complexes of O-Donors ................................ 285 four. 6. 2 Complexes of N-Donors ................................ 285 four. 6. three Tertiary Phosphine and Arsine Complexes .................................................... 286 four. 6. four Complexes of Halogen-Donors ...................... 287 four. 6. five Complexes of C-Donors ................................ 288 four. 6. 6 Complexes of S-Donors ................................. 288 four. 7 Silver(II) Complexes ........................................................ 290 four. eight Silver(III) Complexes ....................................................... 291 four. nine Gold(-I) Complexes ......................................................... 291 four. 10 Gold(I) Complexes .......................................................... 292 four. 10. 1 Complexes of O-Donors ................................ 292 four. 10. 2 Complexes of N-Donors ................................ 292 four. 10. three Tertiary Phosphine and Arsine Complexes .................................................... 292 four. 10. four Complexes of Halogen-Donors ...................... 295 four. 10. five Complexes of C-Donors ................................ 296 four. 10. 6 Complexes of S-Donors ................................. 296 four. 10. 7 MO Schemes for 2-Coordinate Gold(I) Complexes .................................................... 298 four. eleven Gold(II) Complexes ......................................................... 298 This web page has been reformatted by means of Knovel to supply more straightforward navigation. Contents xi four. 12 Gold(III) Complexes ........................................................ 301 four. 12. 1 Complexes of Halogens ................................. 301 four. 12. 2 Complexes of N-Donors ................................ 302 four. 12. three Tertiary Phosphine and Arsine Complexes .................................................... 303 four. 12. four different Complexes .......................................... 304 four. 12. five Coordination Numbers and Gold(III) ............... 305 four. 12. 6 The trans-Effect and trans-Influence ..............

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